Kigali is the capital and largest city of Rwanda. It is near the nation's geographic centre in a region of rolling hills, with a series of valleys a…Kigali is the capital and largest city of Rwanda. It is near the nation's geographic centre in a region of rolling hills, with a series of valleys and ridges joined by steep slopes. As a primate city, Kigali is a relatively new city. It has been Rwanda's economic, cultural, and transport hub since it was founded as an administrative outpost in 1907, and became the capital of the country at independence in 1962, shifting focus away from Huye.